The influence of preliminary heat treatment on morphology of carbon layer formed on surface of chlorinated polyvinyl chloride under the impact of a high-power ion beam
https://doi.org/10.25206/1813-8225-2023-188-125-131
EDN: WCVTCI
Abstract
The effect of preliminary heat treatment on the morphology of carbon layer formed on the surface of chlorinated polyvinyl chloride with the addition of ferrocene (10 % of polymer weight) under the impact of a high-power nanosecond-durable ion beam has been studied. Preliminary exposure of samples in an oven at different temperatures for 1 hour leads to partial dehydrochlorination of the surface layer of the polymer film and interchain crosslinking, creating centers for the start of the carbonization reaction, and thus affects the formation of carbon nanostructures during subsequent irradiation with a high-power ion beam. The possible mechanism of carbon nanostructures formation from chlorinated polyvinyl chloride under the impact of a high-power ion beam and the mechanism of the influence of preliminary heat treatment on it are considered. It has been established that different heat treatment temperatures lead to different morphologies of the resulting carbon nanostructures. On the control sample and the sample subjected to heating to 100 °C, only nanofibers are formed, preheating to 150 °C leads to the formation of a porous structure with nanosized pores under the nanofibers, and preheating to 200 °C leads to a significant decrease in the porosity and concentration of nanofibers.
About the Authors
V. S. Kovivchak
Dostoevsky Omsk State University; Omsk Scientific Center SB RAS
Russian Federation
Russian Federation
Vladimir S. Kovivchak - Candidate of Physics and Mathematics Sciences, Associate Professor, Associate Professor of General and Experimental Physics Department, Dostoevsky Omsk State University (OmSU); Senior Researcher of Functional Electronics Laboratory, Institute of Radiophysics and Physical Electronics, Omsk Scientific Center SB RAS.
Omsk
AuthorID (RSCI) 37657
AuthorID (SCOPUS) 6603186738
ResearcherID A-3942-2014
A. A. Parygin
Dostoevsky Omsk State University
Russian Federation
Russian Federation
Arkadiy A. Parygin - Graduate Student in the field Physics and Astronomy, OmSU.
Omsk
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Review
For citations:
Kovivchak V.S., Parygin A.A. The influence of preliminary heat treatment on morphology of carbon layer formed on surface of chlorinated polyvinyl chloride under the impact of a high-power ion beam. Omsk Scientific Bulletin. 2023;(4):125-131. (In Russ.) https://doi.org/10.25206/1813-8225-2023-188-125-131. EDN: WCVTCI
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